Rust Monsters have acidic claws
Those sound like they hurt
The in-game description of (normal) rust monsters is as follows: "The rust monsters used to live in a lone mountain range in an outlying district of Ancardia. On one of their seasonal migrations, they were trapped in the Drakalor Chain by the forces of Chaos. Unfortunately, their new home is very ill suited to their health. Their diet requires a complex cocktail of trace elements, minerals, ores and metals which are hard to find outside their native biotope. With their acid-dripping claws, they try to etch these substances from rock seams in the dungeons, but due to a very poor yield, they had to resort to attacking every adventurer with a promising looking backpack. Don't let them touch you; their corrosive grip will ruin your weapons and armor. Be generous and feed them, and they will soon calm down."
It stands to reason from their abilities that the particular variety of acid they use is especially corrosive to iron-based metals compared to other kinds of acids in ADOM. It also stands to reason, based on their description, that being hit by one (or by one of its more powerful cousins) should cause acid damage to a non-resistant PC in addition to... er... claw damage.